Hi Kevin!
ALMComplete is a web application. You can either purchase our cloud version where we host you on our servers, or your can purchase an "on premises" version where you host your own web application on your own servers.
Anyway - you can export almost anything in ALMComplete to a CSV file.
For the Test Library, all you need to do is go to Test Management, click on Test Library. You can create a filter to select a subset of Tests if you want.
All Tests displayed on the grid listing will be exported.
Click the Actions drop down. You'll see several Export options.
Export Tests (visible fields only) exports the data on the columns that you see plus Step / Expected Results.
Export Tests (all fields) exports all the info on the Test plus Step / Expected Results.
You can do the same with Requirements: go to the Requirements tab and click the Actions drop down, then Export.
Hope this helps!